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1. Melt 2 tablespoons butter in a nonstick skillet over moderate heat. Add pears and cook, turning once, until golden brown, about 5 minutes. Transfer to a plate to cool.
2. Preheat oven to 350 degree F and arrange rack in lower third of oven. Whisk together 4 eggs, the sugar, salt, molasses, syrup, melted butter, and extract; stir in pecans. Pour into piecrust and decoratively arrange pear slices on filling. Bake until filling is puffed and just set, 50 to 55 minutes. Transfer to rack to cool. Best served warm. Makes 8 servings.